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      2-Hydroxyethyl methacrylate (HEMA)

      • Product Name: 2-Hydroxyethyl methacrylate (HEMA)
      • CAS: 868-77-9
      • Purity:
      • Appearance: colourless liquid

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      Factory Sells Best Quality 2-Hydroxyethyl methacrylate (HEMA) 868-77-9 with stock

      • Molecular Formula:C6H10O3
      • Molecular Weight:130.144
      • Appearance/Colour:colourless liquid 
      • Vapor Pressure:0.01 mm Hg ( 25 °C) 
      • Melting Point:-12 °C 
      • Refractive Index:n20/D 1.453(lit.)  
      • Boiling Point:189.031 °C at 760 mmHg 
      • PKA:13.83±0.10(Predicted) 
      • Flash Point:97.222 °C 
      • PSA:46.53000 
      • Density:1.054 g/cm3 
      • LogP:0.09800 

      2-Hydroxyethyl methacrylate(Cas 868-77-9) Usage

      Definition

      2-Hydroxyethyl methacrylate is an enoate ester that is the monomethacryloyl derivative of ethylene glycol.

      General Description

      2-Hydroxyethyl methacrylate (HEMA) is biocompatible in nature. Polymeric hydrogel scaffold can be produced by polymerizing HEMA in water.

      Hazard

      30% grade (with xylene): Flammable, moderate fire risk.

      Purification Methods

      Dissolve the ester in water and extract with n-heptane to remove ethylene glycol dimethacrylate (checked by gas-liquid chromatography and by NMR) and distil it twice under reduced pressure [Strop et al. J Phys Chem 80 694 1976]. [Beilstein 2 IV 1530.]

      InChI:InChI=1/C6H10O3/c1-4(2)6(8)9-5(3)7/h5,7H,1H2,2-3H3

      868-77-9 Relevant articles

      BIOGUM AND BOTANICAL GUM HYDROGEL BIOINKS FOR THE PHYSIOLOGICAL 3D BIOPRINTING OF TISSUE CONSTRUCTS FOR IN VITRO CULTURE AND TRANSPLANTATION

      -

      , (2021/01/20)

      Bioink compositions comprising a biomate...

      Acrylate monomer having hydrophilic end group and a method for preparing the same

      -

      Paragraph 0093-0106; 0128-0132, (2021/11/02)

      More particularly, the present invention...

      Runge-Kutta analysis for optimizing the Zn-catalyzed transesterification conditions of MA and MMA with diols to maximize monoesterified products

      Kato, Taito,Akebi, Shin-Ya,Nagae, Haruki,Yonehara, Koji,Oku, Tomoharu,Mashima, Kazushi

      , p. 6975 - 6986 (2021/11/17)

      Terminal hydroxylated acrylates and meth...

      Method for producing hydroxyethyl methacrylate through ester exchange method

      -

      Paragraph 0015-0045, (2019/01/23)

      The invention discloses a method for pro...

      868-77-9 Process route

      oxirane
      75-21-8,99932-75-9

      oxirane

      poly(methacrylic acid)
      79-41-4,25087-26-7,50867-57-7

      poly(methacrylic acid)

      2-methyl-2-propenoic acid 2-hydroxyethyl ester
      868-77-9,141668-69-1,25736-86-1,82601-55-6,25249-16-5

      2-methyl-2-propenoic acid 2-hydroxyethyl ester

      2-hydroxyethyl acetate
      542-59-6

      2-hydroxyethyl acetate

      2-(2-hydroxyethoxy)ethyl methacrylate
      2351-43-1,25736-86-1

      2-(2-hydroxyethoxy)ethyl methacrylate

      EDMA
      97-90-5,12738-39-5

      EDMA

      Conditions
      Conditions Yield
      10H-phenothiazine; chromium(lll) acetate; at 60 - 80 ℃; for 6.1h; under 750.075 Torr; Autoclave;
      96.0 %Chromat.
      0.08 %Chromat.
      3.7 %Chromat.
      0.3 %Chromat.
      1,2-propanediene
      463-49-0

      1,2-propanediene

      carbon monoxide
      201230-82-2

      carbon monoxide

      ethylene glycol
      107-21-1

      ethylene glycol

      2,2-dimethyl-1,3-dioxolane
      2916-31-6

      2,2-dimethyl-1,3-dioxolane

      2-methyl-2-propenoic acid 2-hydroxyethyl ester
      868-77-9,141668-69-1,25736-86-1,82601-55-6,25249-16-5

      2-methyl-2-propenoic acid 2-hydroxyethyl ester

      Conditions
      Conditions Yield
      dodecacarbonyl-triangulo-triruthenium; at 100 ℃; for 3h;
      52%
      8%

      868-77-9 Upstream products

      • 75-21-8
        75-21-8

        oxirane

      • 79-41-4
        79-41-4

        poly(methacrylic acid)

      • 107-21-1
        107-21-1

        ethylene glycol

      • 80-62-6
        80-62-6

        methacrylic acid methyl ester

      868-77-9 Downstream products

      • 19117-13-6
        19117-13-6

        2-Methyl-acrylic acid 2-(heptyl-{4-[1-(4-{heptyl-[2-(2-methyl-acryloyloxy)-ethoxy]-phosphinoyloxy}-phenyl)-1-methyl-ethyl]-phenoxy}-phosphinoyloxy)-ethyl ester

      • 97789-13-4
        97789-13-4

        Phosphorsaeure-diisoamylester-(2-methacryloyloxy-ethylester)

      • 814-26-6
        814-26-6

        Phosphorsaeure-diisobutylester-(2-methacryloyloxy-ethylester)

      • 15458-75-0
        15458-75-0

        2-(methacryloyloxy)ethyl phosphate

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