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    2. Organic Intermediates: Dye Intermediates

      Home - Products List - Organic Intermediates: Dye Intermediates

      1,4-Phthalaldehyde (Terephthalaldehyde)

      • Product Name: 1,4-Phthalaldehyde (Terephthalaldehyde)
      • CAS: 623-27-8
      • Purity:
      • Appearance: white to light yellow crystalline powder

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      Chinese Manufacturer supply 1,4-Phthalaldehyde (Terephthalaldehyde) 623-27-8 in stock with high standard

      • Molecular Formula:C8H6O2
      • Molecular Weight:134.134
      • Appearance/Colour:white to light yellow crystalline powder 
      • Vapor Pressure:0.027mmHg at 25°C 
      • Melting Point:114-116 °C(lit.) 
      • Refractive Index:1.622 
      • Boiling Point:246.5 °C at 760 mmHg 
      • Flash Point:101.7 °C 
      • PSA:34.14000 
      • Density:1.189 g/cm3 
      • LogP:1.31160 

      Terephthalaldehyde(Cas 623-27-8) Usage

      Synthesis Reference(s)

      Organic Syntheses, Coll. Vol. 3, p. 788, 1955Tetrahedron Letters, 36, p. 2285, 1995 DOI: 10.1016/0040-4039(95)00191-E

      Purification Methods

      Terephthalaldehyde [623-27-8] M 134.1, m 116o, b 245 -248o/771mm. Crystallise terephthalaldehyde from water. [Beilstein 7 IV 2140.]

      InChI:InChI=1/C8H6O2/c9-5-7-1-2-8(6-10)4-3-7/h1-6H

      623-27-8 Relevant articles

      4-(dibromomethyl)benzaldehyde and its reactions with primary amines

      Gazizov,Ivanova, S. Yu.,Bagauva,Karimova,Ibragimov, Sh. N.,Musin

      , p. 2209 - 2211 (2015)

      -

      A lanthanide-functionalized covalent triazine framework as a physiological molecular thermometer

      Abalymov, Anatolii,Abednatanzi, Sara,Bourda, Laurens,Dalapati, Sasanka,Gohari Derakhshandeh, Parviz,Kaczmarek, Anna M.,Liu, Ying-Ya,Meledina, Maria,Skirtach, Andre G.,Van Der Voort, Pascal,Van Hecke, Kristof

      , p. 6436 - 6444 (2021)

      Crystalline covalent triazine frameworks...

      Metal nanoparticles decorated MIL-125-NH2 and MIL-125 for efficient photocatalysis

      Qiu, Jianhao,Yang, Lvye,Li, Ming,Yao, Jianfeng

      , p. 297 - 306 (2019)

      Metal nanoparticles (NPs) decorated MOFs...

      Synthesis of 4-(dibromomethyl)benzenecarbaldehyde and its reactions with N- and O-nucleophiles

      Gazizov,Ivanova, S. Yu.,Karimova,Bagauva,Gazizova,Karimova

      , p. 191 - 194 (2016)

      4-(Dibromomethyl)benzenecarbaldehyde was...

      Nano–silica functionalized with thiol–based dendrimer as a host for gold nanoparticles: An efficient and reusable catalyst for chemoselective oxidation of alcohols

      Haghshenas Kashani, Sara,Landarani-Isfahani, Amir,Moghadam, Majid,Tangestaninejad, Shahram,Mirkhani, Valiollah,Mohammadpoor-Baltork, Iraj

      , (2018)

      In this paper, we present the synthesis ...

      A Magnetically Recyclable Palladium-Catalyzed Formylation of Aryl Iodides with Formic Acid as CO Source: A Practical Access to Aromatic Aldehydes

      You, Shengyong,Zhang, Rongli,Cai, Mingzhong

      supporting information, p. 1962 - 1970 (2021/01/25)

      A magnetically recyclable palladium-cata...

      Liquid-phase oxidation of olefins with rare hydronium ion salt of dinuclear dioxido-vanadium(V) complexes and comparative catalytic studies with analogous copper complexes

      Maurya, Abhishek,Haldar, Chanchal

      , (2021/02/26)

      Homogeneous liquid-phase oxidation of a ...

      Radical induced disproportionation of alcohols assisted by iodide under acidic conditions

      Huang, Yang,Jiang, Haiwei,Li, Teng,Peng, Yang,Rong, Nianxin,Shi, Hexian,Yang, Weiran

      supporting information, p. 8108 - 8115 (2021/10/29)

      The disproportionation of alcohols witho...

      Samarium-based Grignard-type addition of organohalides to carbonyl compounds under catalysis of CuI

      Liu, Chen,Liu, Yongjun,Qi, Yan,Song, Bin,Wang, Liang,Xiao, Shuhuan

      , p. 6169 - 6172 (2021/06/30)

      Grignard-type additions were readily ach...

      623-27-8 Process route

      1,4-Divinylbenzene
      105-06-6

      1,4-Divinylbenzene

      terephthalic acid
      100-21-0

      terephthalic acid

      4-ethenylbenzoic acid
      1075-49-6

      4-ethenylbenzoic acid

      4-vinyl-benzaldehyde
      1791-26-0

      4-vinyl-benzaldehyde

      terephthalaldehyde,
      623-27-8

      terephthalaldehyde,

      Conditions
      Conditions Yield
      With pyridine; dimethylsulfide; oxygen; ozone; Yield given. Multistep reaction; 1.) CH2Cl2, -78 deg C- -75 deg C, 5 hrs., 2.) CH2Cl2, r.t., 2 hrs.;
      terephthaloyl chloride
      100-20-9

      terephthaloyl chloride

      terephthalic acid
      100-21-0

      terephthalic acid

      4-formylbenzoyl chloride
      16173-52-7

      4-formylbenzoyl chloride

      terephthalaldehyde,
      623-27-8

      terephthalaldehyde,

      benzaldehyde
      100-52-7

      benzaldehyde

      4-Carboxybenzaldehyde
      619-66-9

      4-Carboxybenzaldehyde

      Conditions
      Conditions Yield
      With hydrogen; thiourea; palladium on activated charcoal; In xylene; at 110 ℃; Product distribution; effects of catalyst support, solvents, kind of catalyst, and kind of modifier;
      78 % Chromat.

      623-27-8 Upstream products

      • 623-26-7
        623-26-7

        terephthalonitrile

      • 502-86-3
        502-86-3

        p-xylylene

      • 1592-31-0
        1592-31-0

        1,4-bis(dibromomethyl)benzene

      • 589-29-7
        589-29-7

        p-xylylene glycol

      623-27-8 Downstream products

      • 16323-43-6
        16323-43-6

        1,4-phenylenediacrylic acid

      • 2695-78-5
        2695-78-5

        1,4-bis-(2,4-dinitro-styryl)-benzene

      • 27069-35-8
        27069-35-8

        1,4-bis-[trans-2-(1-methyl-pyridinium-2-yl)-vinyl]-benzene; diiodide

      • 23359-08-2
        23359-08-2

        4-formylcinnamic acid

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