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      2,4-Dimethylphenol

      • Product Name: 2,4-Dimethylphenol
      • CAS: 105-67-9
      • Purity:
      • Appearance: clear colorless to yellow liquid

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      Reliable factory customized supply 2,4-Dimethylphenol 105-67-9

      • Molecular Formula:C8H10O
      • Molecular Weight:122.167
      • Appearance/Colour:clear colorless to yellow liquid 
      • Vapor Pressure:0.093mmHg at 25°C 
      • Melting Point:22-23 ºC 
      • Refractive Index:n20/D 1.538(lit.)  
      • Boiling Point:210.9 ºC at 760 mmHg 
      • Flash Point:85.6 ºC 
      • PSA:20.23000 
      • Density:1.014 g/cm3 
      • LogP:2.00900 

      2,4-Xylenol(Cas 105-67-9) Usage

      Use Description

      2,4-Xylenol, a specific chemical compound, serves distinct roles in various fields. In the realm of industrial chemistry, it plays a significant role as a precursor in the synthesis of antioxidants, resins, and specialty chemicals used in various applications, contributing to the enhancement of product stability and performance. In the field of disinfection and sanitation, 2,4-xylenol is utilized as an antimicrobial agent in cleaning products and disinfectants, aiding in the elimination of bacteria and pathogens from surfaces. Moreover, in the fragrance and flavor industries, this compound can serve as a raw material for the creation of scents and flavors that find application in a wide range of products. Its applications in industrial chemistry, disinfection, and fragrances underscore its importance in improving product properties, ensuring hygiene, and enhancing sensory experiences within these distinct domains.

      InChI:InChI=1/C8H10O/c1-6-4-3-5-8(9)7(6)2/h3-5,9H,1-2H3

      105-67-9 Relevant articles

      Sodium perborate: A convenient reagent for benzylic hydroperoxide rearrangement

      Kabalka,Reddy,Narayana

      , p. 7667 - 7668 (1993)

      Sodium perborate in boron trifluoride et...

      Catalytic oxidation of aromatic hydrocarbons by a molecular iron-NHC complex

      Lindhorst, Anja C.,Schütz, Jan,Netscher, Thomas,Bonrath, Werner,Kühn, Fritz E.

      , p. 1902 - 1911 (2017)

      An iron-NHC complex bearing a tetradenta...

      Photochemical reactions of oxygen atoms with toluene, m-xylene, p-xylene, and mesitylene: An infrared matrix isolation investigation

      Parker, James K.,Davis, Steven R.

      , p. 4108 - 4114 (2000)

      The photochemical reactions of oxygen at...

      One-pot synthesis of phenols by hydroxylation of aromatics with hydroxylamine

      Zhang, Dongsheng,Gao, Liya,Xue, Wei,Zhao, Xinqiang,Wang, Shufang,Wang, Yanji

      , p. 369 - 371 (2012)

      In this study, a new approach for one-po...

      Application of two morphologies of Mn2O3for efficient catalyticortho-methylation of 4-chlorophenol

      Gui, Wenying,Liu, Xiaofei,Wang, Zhenlu,Zhang, Chunlei,Zhang, Hongqiang,Zhang, Li,Zhu, Wanchun

      , p. 20836 - 20849 (2021)

      Vapor phaseortho-methylation of 4-chloro...

      The role of ion-molecule pair intermediates in acid-catalyzed solvolysis. General base-catalyzed formation of 4-methylbenzyl carbocation and its trapping by nucleophiles

      Thibblin

      , p. 7427 - 7433 (1993)

      The specific acid-catalyzed hydrolysis o...

      -

      Simons,McArthur

      , p. 364 (1947)

      -

      Synthesis of substituted phenols via hydroxylation of arenes using hydrogen peroxide in the presence of hexaphenyloxodiphosphonium triflate

      Khodaei, Mohammad Mehdi,Alizadeh, Abdolhamid,Hezarkhani, Hadis Afshar

      , p. 878 - 882 (2018)

      A mild and efficient protocol for the sy...

      Evaluation of acute toxicity and genotoxicity of liquid products from pyrolysis of Eucalyptus grandis wood

      Pimenta,Bayona,Garcia,Solanas

      , p. 169 - 175 (2000)

      Slow pyrolysis of Eucalyptus grandis woo...

      Photoinduced Decomposition of Peracetic Acid in Xylenes. Orientation in Aromatic Substitution of Methyl and Hydroxyl Radicals

      Ogata, Yoshiro,Tomizawa, Kohtaro

      , p. 785 - 788 (1980)

      The photolysis of peracetic acid (1) in ...

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      Lambooy

      , p. 5327 (1950)

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      Highly Selective and Efficient Ring Hydroxylation of Alkylbenzenes with Hydrogen Peroxide and an Osmium(VI) Nitrido Catalyst

      Kwong, Hoi-Ki,Lo, Po-Kam,Yiu, Shek-Man,Hirao, Hajime,Lau, Kai-Chung,Lau, Tai-Chu

      , p. 12260 - 12263 (2017)

      The OsVI nitrido complex, OsVI(N)(quin)2...

      Phenylthioalkylation-Desulphurisation for the C-Alkylation of Phenols

      Fleming, Ian,Iqbal, Javed

      , p. 937 - 939 (1982)

      -

      Effect of Co incorporation and support selection on deoxygenation selectivity and stability of (Co)Mo catalysts in anisole HDO

      Ranga, Chanakya,Alexiadis, Vaios I.,Lauwaert, Jeroen,L?deng, Rune,Thybaut, Joris W.

      , p. 61 - 70 (2019)

      A series of supported Co modified Mo cat...

      Efficient Transformation of Anisole into Methylated Phenols over High-Silica HY Zeolites under Mild Conditions

      Meng, Qinglei,Fan, Honglei,Liu, Huizhen,Zhou, Huacong,He, Zhenhong,Jiang, Zhiwei,Wu, Tianbin,Han, Buxing

      , p. 2831 - 2835 (2015)

      Transformation of anisole (methoxybenzen...

      Synthesis of mono- and polycyclic tricarbonyliron cyclohexa-2,4-dienone complexes and phenols from tosylhydrazones of acyclic dienone complexes

      Franck-Neumann, Michel,Geoffroy, Philippe,Gassmann, Dominique

      , p. 2054 - 2058 (2002)

      Cyclohexa-2,4-dienones stabilized by coo...

      A new mild deprotecting method for O-benzylsulfonyl phenols and alcohols based on a DTBB-catalyzed lithiation

      Alonso, Francisco,Moglie, Yanina,Vitale, Cristian,Radivoy, Gabriel,Yus, Miguel

      , p. 1971 - 1976 (2005)

      A variety of alcohols and phenols, prote...

      Carbonyl Oxide Chemistry. The NIH Shift

      Kumar, S.,Murray, R. W.

      , p. 1040 - 1045 (1984)

      Benzophenone oxide has been shown to oxi...

      Acid-Catalyzed Dehydration of Substituted Dienediols

      Wigal, Carl T.,McKinley, Jason D.,Coyle, Jennifer,Porter, Diane J.,Lehman, Daniel E.

      , p. 8421 - 8423 (1995)

      -

      -

      Gassmann,Amick

      , p. 889 (1974)

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      ipso-Attack in the Hydroxylation of o- and p-Xylene using bis(trimethylsilyl) Peroxide and Aluminium Chloride

      Apatu, Jonas O.,Chapman, David C.,Heaney, Harry

      , p. 1079 - 1080 (1981)

      Electrophilic hydroxylation of o- and p-...

      Oxyfunctionalization of Hydrocarbons. 11. Hydroxylation of Benzene and Alkylbenzenes with Hydrogen Peroxide in Hydrogen Fluoride/Boron Trifluoride

      Olah, George A.,Fung, Alexander P.,Keumi, Takashi

      , p. 4305 - 4306 (1981)

      -

      Improved oxidation of aromatic and aliphatic hydrocarbons using rate enhancing variants of P450Bm3 in combination with decoy molecules

      Munday, Samuel D.,Shoji, Osami,Watanabe, Yoshihito,Wong, Luet-Lok,Bell, Stephen G.

      , p. 1036 - 1039 (2016)

      Enzyme performance can be improved using...

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      Vesely,Schmerling

      , p. 4028,4030 (1970)

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      Comparison of cresol transformation on USHY and HZSM-5

      Imbert,Guisnet,Gnep

      , p. 279 - 286 (2000)

      In the commercial synthesis of cresols, ...

      PHOTOCHEMICAL ELECTRON TRANSFER REACTIONS OF 4-TRICHLOROMETHYL-4-METHYL-2,5-CYCLOHEXADIEN-1-ONES

      Schuster, David I.,Brisimitzakis, Angelo C.

      , p. 4531 - 4534 (1982)

      Ultraviolet irradiation of the title com...

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      Harris,Saeman,Bergstrom

      , p. 2063,2065 (1949)

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      Ortho-alkylation of phenol with methanol using Pb-Cr promoted magnesium oxide catalysts

      Ke, Jyh-Harng,Zena, Jyh-Myng,Wang, Fey-Long

      , p. 1407 - 1410 (2004)

      In this study, Pb-Cr promoted magnesium ...

      Palladium-catalyzed hydroxylation of aryl and heteroaryl halides enabled by the use of a palladacycle precatalyst

      Cheung, Chi Wai,Buchwald, Stephen L.

      , p. 5351 - 5358 (2014)

      A method for the hydroxylation of aryl a...

      Catalytic Activation of Unstrained C(Aryl)-C(Alkyl) Bonds in 2,2′-Methylenediphenols

      Dong, Guangbin,Ratchford, Benjamin L.,Xue, Yibin,Zhang, Rui,Zhu, Jun

      supporting information, p. 3242 - 3249 (2022/02/23)

      Catalytic activation of unstrained and n...

      REARRANGEMENT OF DIMETHYLPHENYLACYLATES USING ZEOLITES

      -

      Page/Page column 9-10; 12, (2021/08/14)

      The present invention relates to a Fries...

      Ceria-promoted Co@NC catalyst for biofuel upgrade: synergy between ceria and cobalt species

      Wang, Bowei,Gao, Ruixiao,Zhang, Dan,Zeng, Yuyao,Zhang, Fangying,Yan, Xilong,Li, Yang,Chen, Ligong

      supporting information, p. 8541 - 8553 (2021/04/12)

      Ceria-promoted Co@NC (NC, N doped carbon...

      105-67-9 Process route

      sodium[tetrakis(2,4-dimethylphenyloxy)borate]

      sodium[tetrakis(2,4-dimethylphenyloxy)borate]

      2,2'-dihydroxy-3,3',5,5'-tetramethylbiphenyl
      26567-10-2

      2,2'-dihydroxy-3,3',5,5'-tetramethylbiphenyl

      2,4-Xylenol
      105-67-9

      2,4-Xylenol

      Conditions
      Conditions Yield
      sodium[tetrakis(2,4-dimethylphenyloxy)borate]; In N,N-dimethyl-formamide; at 20 ℃; Electrolysis;
      With citric acid; In water; N,N-dimethyl-formamide; for 0.0833333h;
      65%
      2%
      sodium[tetrakis(2,4-dimethylphenyloxy)borate]; In acetonitrile; at 40 ℃; Electrolysis;
      With citric acid; In water; acetonitrile; for 0.0833333h;
      63 % Chromat.
      28 % Chromat.
      sodium[tetrakis(2,4-dimethylphenyloxy)borate]

      sodium[tetrakis(2,4-dimethylphenyloxy)borate]

      Pummerer's ketone

      Pummerer's ketone

      2,2'-dihydroxy-3,3',5,5'-tetramethylbiphenyl
      26567-10-2

      2,2'-dihydroxy-3,3',5,5'-tetramethylbiphenyl

      2,4-Xylenol
      105-67-9

      2,4-Xylenol

      Conditions
      Conditions Yield
      sodium[tetrakis(2,4-dimethylphenyloxy)borate]; In acetonitrile; at 20 ℃; Electrolysis;
      With citric acid; In water; acetonitrile; for 0.0833333h;
      24%
      4%
      2%

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        1,2,4-Trimethylbenzene

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